Please use this identifier to cite or link to this item:
http://hdl.handle.net/2307/348
DC Field | Value | Language |
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dc.contributor.author | Corradini, Dario | - |
dc.contributor.author | Gallo, Paola | - |
dc.contributor.author | Rovere, Mauro | - |
dc.date.accessioned | 2010-07-26T10:24:54Z | - |
dc.date.available | 2010-07-26T10:24:54Z | - |
dc.date.issued | 2009 | - |
dc.identifier.issn | 0021-9606 | - |
dc.identifier.uri | http://hdl.handle.net/2307/348 | - |
dc.description.abstract | Molecular dynamics simulations are performed on two sodium chloride solutions in TIP4P water with concentrations c=1.36 mol/kg and c=2.10 mol/kg upon supercooling. The isotherms and isochores planes are calculated. The temperature of maximum density line and the limit of mechanical stability line are obtained from the analysis of the thermodynamic planes. The comparison of the results shows that for densities well above the limit of mechanical stability, the isotherms and isochores of the sodium chloride aqueous solution shift to lower pressures upon increasing concentration while the limit of mechanical stability is very similar to that of bulk water for both concentrations. We also find that the temperature of maximum density line shifts to lower pressures and temperatures upon increasing concentration. Indications of the presence of a liquid-liquid coexistence are found for both concentrations. | en |
dc.language.iso | en | en |
dc.publisher | American Institue of Physics | en |
dc.relation.ispartof | The journal of chemical physics | en |
dc.rights | c2009 American Institute of Physics | en |
dc.subject | MOLECULAR-DYNAMICS SIMULATIONS | en |
dc.subject | LIQUID PHASE-TRANSITION | en |
dc.subject | EQUATION-OF-STATE | en |
dc.subject | STRUCTURAL-CHARACTERIZATION | en |
dc.subject | ELECTROLYTE-SOLUTIONS | en |
dc.subject | GLASS-TRANSITION | en |
dc.subject | ION ASSOCIATION | en |
dc.subject | WATER-STRUCTURE | en |
dc.subject | NACL SOLUTION | en |
dc.subject | TEMPERATURE | en |
dc.title | Effect of concentration on the thermodynamics of sodium chloride aqueous solutions in the supercooled regime | en |
dc.type | Article | en |
dc.subject.miur | Settori Disciplinari MIUR::Scienze fisiche::FISICA DELLA MATERIA | en |
dc.subject.miur | Scienze fisiche | - |
dc.subject.isicrui | Categorie ISI-CRUI::Scienze fisiche::Applied Physics/Condensed Matter/Materials Science | en |
dc.subject.isicrui | Scienze fisiche | - |
dc.subject.anagraferoma3 | Scienze fisiche | en |
dc.relation.volumenumber | 130 | en |
dc.relation.pagenumber | 154511 | en |
dc.identifier.doi | 10.1063/1.3119634 | - |
dc.relation.issuenumber | 15 | en |
dc.description.romatrecurrent | Dipartimento di Fisica 'Edoardo Amaldi' | * |
item.fulltext | With Fulltext | - |
item.languageiso639-1 | other | - |
item.grantfulltext | restricted | - |
Appears in Collections: | A - Articolo su rivista X_Dipartimento di Fisica 'Edoardo Amaldi' |
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JCPcorradini2009.pdf | 202.54 kB | Adobe PDF | Request a copy |
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