Please use this identifier to cite or link to this item:
http://hdl.handle.net/2307/274
DC Field | Value | Language |
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dc.contributor.author | Evangelisti, Claudio | - |
dc.contributor.author | Panziera, Nicoletta | - |
dc.contributor.author | Pertici, Paolo | - |
dc.contributor.author | Vitulli, Giovanni | - |
dc.contributor.author | Salvadori, Piero | - |
dc.contributor.author | Battocchio, Chiara | - |
dc.contributor.author | Polzonetti, Giovanni | - |
dc.date.accessioned | 2010-07-08T10:43:55Z | - |
dc.date.available | 2010-07-08T10:43:55Z | - |
dc.date.issued | 2009-03 | - |
dc.identifier.issn | 0021-9517 | - |
dc.identifier.uri | http://hdl.handle.net/2307/274 | - |
dc.description.abstract | Palladium nanoparticles, obtained by metal vapour synthesis (MVS), weredeposited on cross-linked polyvinylpyridine. The Pd/PVPy system showedhigh catalytic activity in the Heck C-C coupling reaction of iodo- andbromo-arenes (iodobenzene, bromobenzene, p-nitrobromobenzene,p-bromoacetophenone, p-(methoxy)bromobenzene) with alkyl acrylates(methyl acrylate, n-butyl acrylate, ethylhexyltrans-3-(4-methoxyphenyl)acrylate) at 100 degrees C-175 degrees Cworking under nitrogen atmosphere as well as in air. The catalyst isstable and the leaching of metal in solution is very low. When reused,the recovered Pd/PVPy maintains the catalytic activity of the pristinematerial. XPS structural studies performed on the starting catalyst aswell as on the recovered one indicate the presence of a interactionbetween the basic nitrogen of the pyridine present in the polymer andthe metal. (C) 2009 Elsevier Inc. All rights reserved. | en |
dc.language.iso | en | en |
dc.publisher | Elsevier | en |
dc.relation.ispartof | Journal of catalysis | en |
dc.subject | cross-coupling reactions | en |
dc.subject | ray photoelectron-spectroscopy | en |
dc.subject | heterogeneous CATALYSTS | en |
dc.subject | metal-catalysts | en |
dc.subject | PD | en |
dc.title | Palladium nanoparticles supported on polyvinylpyridine: Catalyticactivity in Heck-type reactions and XPS structural studies | en |
dc.type | Article | en |
dc.subject.miur | Settori Disciplinari MIUR::Scienze chimiche | en |
dc.subject.miur | Scienze chimiche | - |
dc.subject.isicrui | Categorie ISI-CRUI::Scienze chimiche | en |
dc.subject.isicrui | Scienze chimiche | - |
dc.subject.anagraferoma3 | Scienze chimiche | en |
dc.relation.volumenumber | 262 | en |
dc.relation.pagenumber | 287-293 | en |
dc.identifier.doi | 10.1016/j.jcat.2009.01.005 | - |
dc.relation.issuenumber | 2 | en |
dc.description.romatrecurrent | Dipartimento di Fisica 'Edoardo Amaldi' | * |
item.languageiso639-1 | other | - |
item.fulltext | With Fulltext | - |
item.grantfulltext | restricted | - |
Appears in Collections: | A - Articolo su rivista X_Dipartimento di Fisica 'Edoardo Amaldi' |
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File | Description | Size | Format | Existing users please Login |
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JCat.pdf | 230.69 kB | Adobe PDF | Request a copy |
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